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Tohoku University Technology:Novel alcohol oxidation catalyst: T12-042

Tohoku University Technology:Novel alcohol oxidation catalyst: T12-042

Enables to effectively oxidize sec-alcohol as well as n-alcohol and to oxidized with air

Alcohol oxidation is one of fundamental reactions in organic chemistry. This reaction is especially useful for synthesizing high-valueadded compounds such as medicine, pesticide, perfume and so on. Although, TEMPO and the related compounds featuring AZADO skeleton (e.g. AZADO, 1-Me-AZADO, and ABNO) are often used as alcohol oxidation catalyst , there are some problems concerning catalytic activity and reaction efficiency. This invention provides novel alcohol oxidation catalyst “Nor-AZADO” which can effectively oxidize sec-alcohol as well as n-alcohol using air as the terminal oxidant.

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Tohoku Univ. Technology :Method for producing tertiary alcohol: T22-005

Tohoku Univ. Technology :Method for producing tertiary alcohol: T22-005

Improved productivity, environmental friendliness and cost reduction

　Tertiary alcohols, such as tert-butyl alcohol (TBA), are useful as starting materials for pharmaceuticals, agrochemicals, and resins because they have higher oxidation resistance and hydroxyl group reactivity than primary/secandary alcohols. As an industrial process, there is a method of radical oxidation of isobutane under high pressure or without catalyst, but this process has problems of high energy load and low selectivity. As a solution, selective oxidation at ambient pressure using gold nanoparticle catalyst in the presence of hydrogen has been reported. However, there is concern about the risk of explosion because hydrogen and oxygen coexist in this method. 　As a result of repeated studies to solve the above problem, the inventor found that isoparaffins can be selectively oxidized using molecular oxygen as an oxidant to produce the corresponding tertiary alcohols with high selectivity and high production rate by using a solid catalyst containing a transition metal oxide of periodic table group 6~9, which does not support gold, and using water instead of conventional hydrogen. In particular, when Co3O4 was used as a catalyst, the selectivity (STAB) of TBA in the product was as high as 99%.

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[Research Document] World Market for Partial Oxidation Catalysts

[Research Document] World Market for Partial Oxidation Catalysts

World Market for Partial Oxidation Catalysts: Activation, Deactivation, Oil Refining, Chemical Industry, Others

This research report (Global Partial Oxidation Catalyst Market) investigates and analyzes the current status and outlook for the global market of partial oxidation catalysts over the next five years. It includes information on the overview of the global partial oxidation catalyst market, trends of major companies (sales, selling prices, market share), market size by segment, market size by major regions, and distribution channel analysis. The segments of the partial oxidation catalyst market by type focus on activation and deactivation, while the segments by application target the oil refining industry, chemical industry, and others. The regional segments are divided into North America, the United States, Europe, Asia-Pacific, Japan, China, India, South Korea, Southeast Asia, South America, the Middle East, and Africa to calculate the market size of partial oxidation catalysts. It also includes the market share of major companies in the partial oxidation catalyst sector, product and business overviews, and sales performance.

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[Research Material] World Market for Environmental Catalysts

[Research Material] World Market for Environmental Catalysts

Global Market for Environmental Catalysts: VOC Oxidation Catalysts, CO Oxidation Catalysts, Selective Catalytic Reduction Catalysts, Others, Manufacturing Industry, Automotive

This research report (Global Environmental Catalysts Market) investigates and analyzes the current state and outlook for the global environmental catalysts market over the next five years. It includes information on the overview of the global environmental catalysts market, trends of major companies (sales, selling prices, market share), market size by segment, market size by major regions, and distribution channel analysis. The market segments by type include VOC oxidation catalysts, CO oxidation catalysts, selective catalytic reduction catalysts, and others, while the segments by application focus on manufacturing and automotive industries. The regional segments are categorized into North America, the United States, Europe, Asia-Pacific, Japan, China, India, South Korea, Southeast Asia, South America, the Middle East, and Africa to calculate the market size for environmental catalysts. It also includes the market share of major companies in the environmental catalysts sector, product and business overviews, and sales performance.

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